Title
Linear alkaline earth metal phosphinate coordination polymers: Synthesis and structural characterization
Document Type
Article
Publication Title
Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials
Publication Date
1-1-2014
Abstract
Reaction of alkaline earth metal salts with diphenylphosphinic acid in dimethylformamide solvent afforded four coordination polymers: [Mg 3(O2PPh2)6(DMF)2] ·2DMF (I), [Ca(O2PPh2)2(DMF) 2] (II), [Sr(O2PPh2)2(DMF) 2] (III) and [Ba(O2PPh2)2(DMF) 2] (IV) (where DMF is N,N-dimethylformamide). Single-crystal X-ray diffraction revealed that all four compounds produce linear chain structures in the solid state, with the Ca, Sr and Ba forming isostructural crystals. The bulk materials were characterized by FT-IR and 1H NMR spectroscopy and elemental analyses. © 2014 International Union of Crystallography.
Volume
70
Issue
3
First Page
602
Last Page
607
DOI
10.1107/S2052520614004247
ISSN
20525192
E-ISSN
20525206
Recommended Citation
Rood, Jeffrey A.; Huttenstine, Ashley L.; Schmidt, Zachery A.; White, Michael R.; and Oliver, Allen G., "Linear alkaline earth metal phosphinate coordination polymers: Synthesis and structural characterization" (2014). Faculty Publications. 1178.
https://jayscholar.etown.edu/facpubharvest/1178
