Title
The role of conformational flexibility in the hypervalency of organosilanes
Document Type
Article
Publication Title
Main Group Metal Chemistry
Publication Date
12-1-2001
Abstract
Organosilanes with the potentially coordinating group -N[(CH 2) 3NMe 2] 2 or -N(CH 2CH 2OMe) 2 have been prepared and characterized by proton, carbon, and silicon NMR spectroscopy. None of the compounds showed evidence of hypervalency, suggesting that the conformationally-flexible bridging framework produces an unfavorable entropy of coordination.
Volume
24
Issue
7
First Page
409
Last Page
411
ISSN
07921241
E-ISSN
21910219
Recommended Citation
Yoder, Claude H.; Schaeffer, Charles D.; Walton, Lisa L.; Falen, Paula L.; Redline, Jennifer K.; Han, Sela; Shah, Meha; Krug, Christopher; and Lao, Sharon D., "The role of conformational flexibility in the hypervalency of organosilanes" (2001). Faculty Publications. 1488.
https://jayscholar.etown.edu/facpubharvest/1488
