Title
Multinuclear NMR spectroscopic studies of some organometallic N-substituted anilines
Document Type
Article
Publication Title
Journal of Organometallic Chemistry
Publication Date
8-4-1992
Abstract
Proton, carbon-13, nitrogen-15, fluorine-19, and silicon-29 NMR chemical shifts and coupling constants are reported for nine N-substituted anilines of the type XC6H4N(H)Y, where X H and F, and Y Si(CH3)3, Ge(CH3)3, Sn(CH3)3, and P(BH3)(CH3)2, and the 15N isotopomer of N-trimethylsilylaniline. Resonances in the natural-abundance carbon-13 NMR spectra for both sets of derivatives are assigned on the basis of additivity relationships, proton-coupled spectra, and relative magnitudes of |J(31P13C)| and |J(19F13C)| coupling constants where appropriate. Carbon-13 and fluorine-19 chemical shifts, and |1J(13C1H)| coupling constants indicate that the P(BH3)(CH3)2 group is substantially electron-withdrawing. © 1992.
Volume
434
Issue
1
First Page
45
Last Page
52
DOI
10.1016/0022-328X(92)83351-H
ISSN
0022328X
Recommended Citation
Barr, Brian K.; Herman, Amy J.; Myers, Lori K.; Young, Pamela I.; Schaeffer, Charles D.; Eppley, Hilary J.; Otter, Julie C.; and Yoder, Claude H., "Multinuclear NMR spectroscopic studies of some organometallic N-substituted anilines" (1992). Faculty Publications. 1542.
https://jayscholar.etown.edu/facpubharvest/1542
